Articles
All articles | Recent articles
Influence of the Chemical Composition of Ceramic Frits on the Kinetics of their Dissolution Process
A. Barba, J.C. Jarque, M. Orduña, M.F. Gazulla
Instituto de Tecnología Cerámica, Asociación de Investigación de las Industrias Cerámicas, Universitat Jaume I, Castellón, España.
received July 13, 2015, received in revised form September 2, 2015, accepted October 5, 2015
Vol. 7, No. 1, Pages 71-78 DOI: 10.4416/JCST2015-00034
Abstract
A study aboutof the influence of the chemical composition of frits ion the kinetics of their dissolution process has been performed, in order to haveobtain an more extensive knowledge about the solubility of different types of frits and to predict their behavior regarding to thewith regard to their dissolution process. The study has been conducted withusing four frits of the most usedfour of the frits most commonly used in the preparation of ceramic glazes: a zirconium white frit, a lead-containing boracic crystalline frit, a crystalline frit containing calcium and zinc and a sodium-containing boracic crystalline frit. The results have been fitted to a kinetic model in which the overall rate of the process is controlled by diffusion except the initial moments of the process, which are controlled by the chemical reaction. The differences inof solubility observed can be explained based onby the differences in the chemical composition of the frits. The kinetic model reproduces the experimental results using adjusting parameters that have physical meaning for the four studied frits.
Download Full Article (PDF)
Keywords
Frit solubility, glass-ceramics, kinetics, glazes,chemical durability
References
1 Barba, A., Jarque, J.C., Orduña, M., Gazulla M.F.: Kinetic model of the dissolution process of a zirconium white frit. influence of the temperature, J. Eur. Ceram. Soc., 35, 751 – 764, (2014).
2 Massera, J., Bourkhis, K., Petit, L., Couzi, M., Hupa, L., Hupa, H., Videau, J.J., Cardinal, T.: Effect of the glass composition on the chemical durability of zinc-phosphate-based glasses in aqueous solutions, J. Phys. Chem. Solids, 74, 121 – 127, (2013).
3 Nourmohammadi, J., Salarian, R., Solati-Hashjin, M., Moztarzadeh, F.: Dissolution behaviour and fluoride release from new glass composition used in glass ionomer cements, Ceram. Int., 33, 557 – 561, (2007).
4 Varila, L., Fagerlund, S., Lehtonen, T., Tuominen, J., Hupa, L.: Surface reactions of bioactive glasses in buffered solutions, J. Eur. Ceram. Soc., 32, 2757 – 2763, (2012).
5 Gin, S., Beaudoux, X., Angeli, F., Jégou, C., Godon, N.: Effect of composition on the short-term and long-term dissolution rates of ten borosilicate glasses of increasing complexity from 3 to 30 oxides, J. Non-Cryst. Solids, 358, 2559 – 2570, (2012).
6 Cailleteau, C., Weige, l.C., Ledieu, A., Barboux, P., Devreux, F.: On the effect of glass composition in the dissolution of glasses by water, J. Non-Cryst. Solids, 354, [2 – 9], 117 – 123, (2008).
7 Hernández Povedano, J.A., Oteo Mazo, J.L.: Reactions of glass surfaces with aqueous solutions, (in Spanish), Bol. Soc. Esp. Ceram. Vidr., 21, [2], 81 – 97, (1982).
8 Fernández Navarro, J.M.: El vidrio: constitución, fabricación y propiedades; 2nd edition. CSIC, Madrid, 1991
9 Strachan, D.M.: Glass dissolution: testing and modelling for long-term behaviour, J. Nucl. Mater., 298, 69 – 77, (2001).
10 Shinkareva, E.V., Bychko, G.V.: Chemical resistance of low-melting enamels for decorating glass products, Glass Ceram+, 62, 9 – 10, (2005).
11 Fröberg, L., Kronberg, T., Törnblom, S., Hupa, L.: Chemical durability of glazed surfaces, J. Eur. Ceram. Soc., 27, [2 – 3], 1811 – 1816, (2007).
12 Hupa, L., Bergman, R., Fröberg, L., Vane-Tempest, S., Hupa, M., Kronberg, T., Pesonen-Leinonen, E., Sjöberg A.M.: Chemical resistance and cleanability of glazed surfaces, Surf. Sci., 584, 113 – 118, (2005).
13 Sanmiguel, F., Ferrando, V., Amorós, J.L., Orts, M.J., Gazulla, M.F., Gómez M.P.: Solubilidad de fritas en suspensiones de esmaltes. Influencia de algunas variables de operación sobre la cinética del proceso, Técnica Cerámica, 275, 689 – 700, (1999).
14 Gómez-Tena, M.P., Bou, E., Moreno, A., Cook, S., Galindo, M.: Nueva materia prima borácica como componente de esmaltes cerámicos. Estudio de su solubilidad en suspensiones acuosas concentradas, Bol. Soc. Esp. Ceram. Vidr., 48, [1], 45 – 52, (2009).
15 Larena, M.T.: Solubilidad en medio acuoso de fritas cerámicas del sistema SiO2-PbO-B2O3. influencia de la composición química de la frita sobre su solubilidad a pH 7, Cerámica Información, 192, 10 – 19, (1993).
16 Huggins, M.L., Sun, K.H.: Calculation of density and optical constants of a glass from its composition in weight percentage, J. Am. Ceram. Soc., 26, [1], 4 – 11, (1943).
17 Gazulla, M.F., Barba, A., Orduña, M., Bautista, Y.: Stability of ceramic glaze compositions. Correlation between partial dissolution and rheological properties. Part I, Glass Technol.-Part A, 53, [3], 101 – 108, (2012).
18 Wen, C.Y.: Noncatalytic heterogeneous solid-fluid reaction models, Ind. Eng. Chem., 60, [9], 34 – 54, (1968).
19 Cable, M., Frade, J.R.: Diffusion controlled mass transfer to or from spheres with concentration-dependent diffusivity, Chem. Eng. Sci., 42, [11], 2525 – 2530, (1987).
20 Leturcq, G., Berger, G., Advocat, T., Fillet, C., Halgand, O., Vernaz, E.: Chemical durability of aluminosilicate glasses containing low solubility chemical elements, Mat. Res. Soc. Symp. Proc., 506, 199 – 206, (1998).
21 Dunken, H., Doremus, R.H.: Short time reactions of a Na2O-CaO-SiO2 glass with water and salt solutions, J. Non-Cryst. Solids, 92, 61 – 72, (1987).
22 Perera, G., Doremus, R.H.: Dissolution rates of silicate glasses in water at pH 7, J. Am. Ceram. Soc., 74, [6], 1269 – 1274, (1991).
Copyright
Göller Verlag GmbH
