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Journal of Ceramic Science and Technology

The Journal of Ceramic Science and Technology publishes original scientific articles on all topics of ceramic science and technology from all ceramic branches. The focus is on the scientific exploration of  the relationships between processing, microstructure and properties of sintered ceramic materials as well as on new processing routes for innovative ceramic materials. The papers may have either theoretical or experimental background. A high quality of publications will be guaranteed by a thorough double blind peer review process.

The Journal is published by Göller Verlag GmbH on behalf of the Deutsche Keramische Gesellschaft (DKG). Edited by Yu-Ping Zeng, Shanghai Institute of Ceramics, Chinese Academy of Sciences, China.

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Influences of Cation Disorder in Commercial Spinel Powders Studied by 27Al MAS NMR on the Sintering of Transparent MgAl2O4 Ceramics

A. Krell1, E. Brendler2

1 Fraunhofer-Institut für Keramische Systeme und Technologien (IKTS, Fraunhofer Institute for Ceramic Systems and Technologies), 01277 Dresden, Germany
2 TU Bergakademie Freiberg (Freiberg University of Mining and Technology), Faculty of Chemistry and Physics, 09599 Freiberg, Germany

received August 16, 2012, received in revised form September 21, 2012, accepted October 14, 2012

Vol. 4, No. 2, Pages 51-58   DOI: 10.4416/JCST2012-00029

Abstract

At the Stockholm Conference of the European Ceramic Society 2011 it was shown that, together with the particle size of raw powders and the homogeneity of particle coordination in the green bodies, the real structure of the lattices is a third major influence on sintering, which may differ significantly even at fixed stoichiometry. Antisite defects govern the whole defect chemistry of MgAl2O4 and should, therefore, affect diffusion and sintering. This possibility is investigated here with solid state 27Al MAS nuclear magnetic resonance measurements of the occupancy of octahedral and tetrahedral sites. Based on previous results with model powders synthesized in order to identify lattice effects at constant particle size distribution, homogeneity and composition, the study has now been extended to commercial spinel powders supplied by Asian, European, and American manufacturers. The results confirm a correlation of increasing cation disorder with improved sintering densification.

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Keywords

Spinel (MgAl2O4), transparency, sintering, antisite defects, 27Al NMR

References

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