• Home
  • Contact
  • Login
  • Privacy
  • Imprint

Search

Journal of Ceramic Science and Technology

The Journal of Ceramic Science and Technology publishes original scientific articles on all topics of ceramic science and technology from all ceramic branches. The focus is on the scientific exploration of  the relationships between processing, microstructure and properties of sintered ceramic materials as well as on new processing routes for innovative ceramic materials. The papers may have either theoretical or experimental background. A high quality of publications will be guaranteed by a thorough double blind peer review process.

The Journal is published by Göller Verlag GmbH on behalf of the Deutsche Keramische Gesellschaft (DKG). Edited by Yu-Ping Zeng, Shanghai Institute of Ceramics, Chinese Academy of Sciences, China.

  • Home
  • Early view
  • Articles
    • All articles
    • Recent Articles
    • Early Views
  • Issues
  • Submit an article
  • Guidelines for Referees
  • Guidelines for Authors
  • Open Access
  • Editorial Board
  • Copyright
  • Contact
  • Order journal / article
  • Customer area
  • Terms of Service

Journal Metrics

Web of science
Impact Factor: 1,220
Impact Factor without Journal Self Cites: 1,060
5 Year Impact Factor: 0,818

Scopus
Scimago Journal Rank (SJR):  0,378

 

Prices

Authors
1,300 € Open Access

Print Subscription
62 € per year

view all subscriptions

 

Payment methods

 Credit card

 Invoice

 Wire transfer

 

Articles

All articles  |  Recent articles

Porous Ceramic Microspheres for Enhancing Acoustic Absorption of Polyurethane Foams in Automotive NVH Control

Qiong Yuan, Shisheng Li

College of Vehicle Engineering, Chongqing Industry Polytechnic University, Chongqing 401120, China

received September 22, 2025, received in revised form October 30, 2025, accepted November 18, 2025

Vol. 17, No. 1, Pages 1-16   DOI: 10.4416/JCST2025-00026

Abstract

Addressing the persistent challenge of lightweight automotive NVH control, this review critically assesses advances in embedding porous ceramic microspheres into polyurethane foams, establishing their efficacy as a high-performance, low-density solution for acoustic packages. We quantify the mechanistic interplay between visco-inertial and thermal losses and key microstructural levers – open porosity, flow resistivity, tortuosity, and cell size/distribution – demonstrating how these hollow inclusions nucleate finer, more uniform cells and introduce crucial internal interfaces, optimizing acoustic impedance. Evidence from impedance-tube studies confirms performance enhancement: lightweight spheres consistently yield high-frequency response gains (≈ 2 – 4 kHz), achieving absorption improvements of ∼ 30 – 50 % at 3.5 kHz, while heavier or larger inclusions enable a strategic frequency shift toward 0.5 – 1 kHz via localized resonance and inertia effects. We conclude that acoustic performance is non-monotonic with filler loading; specifically, modest filler fractions optimize broadband behavior and damping, whereas excessive contents stiffen the polymer frame, promote particle agglomeration, and diminish sub-kilohertz response. Crucially, the rigid ceramic shells provide multifunctional advantages, reinforcing cell walls to increase compressive strength (e.g. from 3.33 MPa to 5.68 MPa), and raising thermal/flame robustness without incurring significant mass penalties. These attributes make the composites highly attractive for critical NVH components such as headliners, pillars, engine covers, wheel-well liners, and emerging EV assemblies. Processing challenges – including dispersion control and balancing openness versus flow resistance – are analyzed alongside opportunities in hybrid micro-nano architectures, property grading through thickness, and model-guided optimization that fuses multiscale structure-property predictions with rapid impedance-tube screening under packaging constraints. This approach has already demonstrated optimal weighted Sound Transmission Loss (STL) reaching 14.02 dB at a thickness of 1 mm, proving the platform's capacity for thin, high-performance NVH solutions. Finally, manufacturability, cost, and sustainability are addressed, noting the appeal of waste-derived cenospheres and compliance pathways (e.g. FMVSS-302), alongside humidity/temperature aging and recyclability. Ultimately, the literature indicates that well-designed microsphere-filled foams can complement or reduce heavy barrier layers, enabling lighter, thinner acoustic packages aligned with emerging EV sound quality targets and durability.

Download Full Article (PDF)

Keywords

Flow resistivity, tortuosity, cell morphology, local resonance, impedance tube

References

1 Gwon, J.G., Kim, S.K., Kim, J.H.: Sound absorption behavior of flexible polyurethane foams with distinct cellular structures, Mater. Des., 89, 448 – 454, (2016). doi: https://doi.org/10.1016/j.matdes.2015.10.017

2 Lin, J.-H., Hsu, P.-Y., Huang, C.-H., Lai, M.-F., Shiu, B.-C., Lou, C.-W.: Functional hollow ceramic Microsphere/Flexible polyurethane foam composites with a cell Structure: mechanical property and sound absorptivity, Polymers, 14, 913, (2022). doi: https://doi.org/10.3390/polym14050913

3 Sung, G., Kim, S.K., Kim, J.W., Kim, J.H.: Effect of isocyanate molecular structures in fabricating flexible polyurethane foams on sound absorption behavior, Polym. Test., 53, 156 – 164, (2016). doi: https://doi.org/10.1016/j.polymertesting.2016.05.028

4 Tian, H., Yao, Y., Zhang, S., Wang, Y., Xiang, A.: Enhanced thermal stability and flame resistance of rigid polyurethane-imide foams by varying copolymer composition, Polym. Test., 67, 68 – 74, (2018). doi: https://doi.org/10.1016/j.polymertesting.2018.02.020

5 Choi, H.J., Kim, J.H.: Sound absorption improvement of polyurethane foam through sequential arrangement of its cellular morphology, Korean J. Chem. Eng., 39, 1072 – 1077, (2022). doi: https://doi.org/10.1007/s11814-021-0974-2

6 Yang, H., Jiang, Y., Liu, H., Xie, D., Wan, C., Pan, H., et al.: Mechanical, thermal and fire performance of an inorganic-organic insulation material composed of hollow glass microspheres and phenolic resin, J. Colloid Interface Sci., 530, 163 – 170, (2018). doi: https://doi.org/10.1016/j.jcis.2018.06.075

7 Estravís, S., Tirado-Mediavilla, J., Santiago-Calvo, M., Ruiz-Herrero, J.L., Villafañe, F., Rodríguez-Pérez, M.Á.: Rigid polyurethane foams with infused nanoclays: relationship between cellular structure and thermal conductivity, Eur. Polym. J., 80, 1 – 15, (2016). doi: https://doi.org/10.1016/j.eurpolymj.2016.04.026

8 Sung, G., Kim, J.W., Kim, J.H.: Fabrication of polyurethane composite foams with magnesium hydroxide filler for improved sound absorption, J. Ind. Eng. Chem., 44, 99 – 104, (2016). doi: https://doi.org/10.1016/j.jiec.2016.08.014

9 Imran, M., Kanti Bandyopadhyay, A., Karan Singh Gandhi, T., Rahaman, A., Rehaan Chandan, M.: Mechanical property enhancement of flexible polyurethane foam using alumina particles, Mater. Today Proc., 45, 4040 – 4044, (2021). doi: https://doi.org/10.1016/j.matpr.2020.10.754

10 Wang, L., Aslani, F., Hajirasouliha, I., Roquino, E.: Ultra-lightweight engineered cementitious composite using waste recycled hollow glass microspheres, J. Clean. Prod., 249, 119331, (2020). doi: https://doi.org/10.1016/j.jclepro.2019.119331

11 Sun, K., Wang, L., Wei, G., Zhang, Q., Wei, Z., Wang, B., et al.: Recent advances and future trends in enhancing the compressive strength of aluminum matrix foam composites reinforced with ceramic hollow spheres: A review, Compos. Struct., 331, 117918, (2024). doi: https://doi.org/10.1016/j.compstruct.2024.117918

12 Lisyutin, V.A., Lastovenko, O.R.: Assessing the influence of internal and viscous friction on dispersion and sound attenuation in unconsolidated marine sediments, Acoust. Phys., 66, 401 – 415, (2020). doi: https://doi.org/10.1134/S1063771020040065

13 Tang, Q., Wang, K., Yaseen, M., Tong, Z., Cui, X.: Synthesis of highly efficient porous inorganic polymer microspheres for the adsorptive removal of Pb2+ from wastewater, J. Clean. Prod., 193, 351 – 362, (2018). doi: https://doi.org/10.1016/j.jclepro.2018.05.094

14 Fomenko, E.V., Anshits, N.N., Vasilieva, N.G., Mikhaylova, O.A., Rogovenko, E.S., Zhizhaev, A.M., et al.: Characterization of fly ash cenospheres produced from the combustion of ekibastuz coal, Energy Fuels, 29, 5390 – 5403, (2015). doi: https://doi.org/10.1021/acs.energyfuels.5b01022

15 Ma, C., Shi, D., Wang, M., He, D., Li, C., Yu, X.: Research on improving NVH performance of automobile side door glass in use based on 6 sigma method, Materials, 14, 3748, (2021). doi: https://doi.org/10.3390/ma14133748

16 Yan, S., He, P., Jia, D., Wang, Q., Liu, J., Yang, J., et al.: Synthesis of novel low-cost porous gangue microsphere/geopolymer composites and their adsorption properties for dyes, Int. J. Appl. Ceram. Technol., 15, 1602 – 1614, (2018). doi: https://doi.org/10.1111/ijac.13045

17 Colombo, P.: Conventional and novel processing methods for cellular ceramics, Philos. Trans. R. Soc. A: Math. Phys. Eng. Sci., 364, 109 – 124, (2005). doi: https://doi.org/10.1098/rsta.2005.1683

18 Hua, K., Chen, X., Shui, A., Xi, X., Gao, P., Zheng, Y., et al.: Preparation and properties of high sound-absorbing porous ceramics reinforced by in situ mullite whisker from construction waste, Molecules, 29, 3419, (2024). doi: https://doi.org/10.3390/molecules29143419

19 Khaleel, M., Soykan, U., Çetin, S.: Influences of turkey feather fiber loading on significant characteristics of rigid polyurethane foam: thermal degradation, heat insulation, acoustic performance, air permeability and cellular structure, Constr. Build. Mater., 308, 125014, (2021). doi: https://doi.org/10.1016/j.conbuildmat.2021.125014

20 Jiang, F., Yu, T., Wang, C., Cao, M., Wang, Z., Chang, Y., et al.: Acoustic/mechanical properties of polyurethane composites with syntactic hollow spheres, Polym. Adv. Technol., 32, 1363 – 1371, (2021). doi: https://doi.org/10.1002/pat.5182

21 Choe, H., Lee, J.H., Kim, J.H.: Polyurethane composite foams including CaCO3 fillers for enhanced sound absorption and compression properties, Compos. Sci. Technol., 194, 108153, (2020). doi: https://doi.org/10.1016/j.compscitech.2020.108153

22 Gao, G., Hu, Y., Jia, H., Liu, P., Du, P., Xu, D.: Acoustic and dielectric properties of epoxy resin/hollow glass microsphere composite acoustic materials, J. Phys. Chem. Solids, 135, 109105, (2019). doi: https://doi.org/10.1016/j.jpcs.2019.109105

23 Yan, S., Pan, Y., Wang, L., Liu, J., Zhang, Z., Huo, W., et al.: Synthesis of low-cost porous ceramic microspheres from waste gangue for dye adsorption, J. Adv. Ceram., 7, 30 – 40, (2018).

24 Pakdel, E., Naebe, M., Kashi, S., Cai, Z., Xie, W., Yuen, A.C.Y., et al.: Functional cotton fabric using hollow glass microspheres: focus on thermal insulation, flame retardancy, UV-protection and acoustic performance, Prog. Org. Coat., 141, 105553, (2020). doi: https://doi.org/10.1016/j.porgcoat.2020.105553

25 Hyuk Park, J., Suh Minn, K., Rae Lee, H., Hyun Yang, S., Bin Yu, C., Yeol Pak, S., et al.: Cell openness manipulation of low density polyurethane foam for efficient sound absorption, J. Sound Vib., 406, 224 – 236, (2017). doi: https://doi.org/10.1016/j.jsv.2017.06.021

26 Wang, W., Liu, H., Gu, W.: A novel fabrication approach for improving the mechanical and sound absorbing properties of porous sound-absorbing ceramics, J. Alloys Compd., 695, 2477 – 2482, (2017). doi: https://doi.org/10.1016/j.jallcom.2016.11.147

27 Zhou, J., Li, X., Chen, C., Zhou, W., Fielitz, T.R., Braun, P.V., et al.: Thermal conductivity of polyurethane thin films, Macromolecules, 57, 6838 – 6847, (2024).

28 Leszczyńska, M., Ryszkowska, J., Szczepkowski, L., Kurańska, M., Prociak, A., Leszczyński, M.K., et al.: Cooperative effect of rapeseed oil-based polyol and egg shells on the structure and properties of rigid polyurethane foams, Polym. Test., 90, 106696, (2020). doi: https://doi.org/10.1016/j.polymertesting.2020.106696

29 Yang, M., Li, J., Man, Y., Peng, Z., Zhang, X., Luo, X.: A three-dimensional mullite-whisker network ceramic with ultra-light weight and high-strength prepared by the foam-gelcasting method, J. Asian Ceram. Soc., 8, 387 – 395, (2020). doi: https://doi.org/10.1080/21870764.2020.1747690

30 Mohammadi, B., Ershad-Langroudi, A., Moradi, G., Safaiyan, A., Habibi, P.: Mechanical and sound absorption properties of open-cell polyurethane foams modified with rock wool fiber, J. Build. Eng., 48, 103872, (2022). doi: https://doi.org/10.1016/j.jobe.2021.103872

31 Baek, S.H., Kim, J.H.: Polyurethane composite foams including silicone-acrylic particles for enhanced sound absorption via increased damping and frictions of sound waves, Compos. Sci. Technol., 198, 108325, (2020). doi: https://doi.org/10.1016/j.compscitech.2020.108325

32 Shaid Sujon, M.A., Islam, A., Nadimpalli, V.K.: Damping and sound absorption properties of polymer matrix composites: A review, Polym. Test., 104, 107388, (2021). doi: https://doi.org/10.1016/j.polymertesting.2021.107388

33 Yadav, G., Agarwal, K., Gupta, S.K.: Structural and thermal stability of functionalized graphene incorporated polyurethane nanocomposite foam, Comput. Mech. Comput. Appl. Int. J., 14, (2023). doi: https://doi.org/10.1615/CompMechComputApplIntJ.2023044759

34 Han, X., Wang, D., Chen, X., Nie, S., Huyan, C., Liu, D., et al.: High damping polyurethane elastomers with wide temperature ranges, Polymer, 325, 128307, (2025). doi: https://doi.org/10.1016/j.polymer.2025.128307

35 Gejguš, T., Schröder, J., Loos, K., Lion, A., Johlitz, M.: Advanced characterisation of soft polymers under cyclic loading in context of engine mounts, Polymers, 14, 429, (2022). doi: https://doi.org/10.3390/polym14030429

36 Song, M.-X., Xie, L.-J., Cheng, J.-Y., Yi, Z.-L., Song, G., Jia, X.-Y., et al.: Insights into the thermochemical evolution of maleic anhydride-initiated esterified starch to construct hard carbon microspheres for lithium-ion batteries, J. Energy Chem., 66, 448 – 458, (2022). doi: https://doi.org/10.1016/j.jechem.2021.08.050

37 Crolla, D., Foster, D., Kobayashi, T., Vaughan, N.: Encyclopedia of automotive engineering, Choice Rev. Online, 53, 53 – 1072, (2015). doi: https://doi.org/10.5860/choice.191861

38 Pinardi, D.: A human head shaped array of microphones and cameras for automotive applications, 2021 Immersive and 3D Audio: from Architecture to Automotive (I3DA), 1 – 8, (2021). doi: https://doi.org/10.1109/I3DA48870.2021.9610879

39 Zhang, S., Li, Y., Jiang, H., He, F., Xu, L., Xiong, F., et al.: Research on the characteristics of EV interior sound quality and its dynamic active control system design and development under accelerated driving conditions, PLoS One, 19, e0290150, (2024). doi: https://doi.org/10.1371/journal.pone.0290150

40 Yan, L., Chen, Z., Zou, Y., He, X., Cai, C., Yu, K., et al.: Field study of the interior noise and vibration of a metro vehicle running on a Viaduct: A case study in guangzhou, Int. J. Environ. Res. Public Health, 17, 2807, (2020). doi: https://doi.org/10.3390/ijerph17082807

41 Wilk-Jakubowski, J.L., Kuchcinski, A., Pawlik, L., Wilk-Jakubowski, G.: Advanced sound insulating Materials: an analysis of material types and properties, Appl. Sci., 15, 6156, (2025). doi: https://doi.org/10.3390/app15116156

42 Mordillat, P., Errico, F., Zerrad, M.: Underbody contribution simulation for vehicle wind-noise, NOISE-CON Proc., 270, 7306 – 7317, (2024). https://doi.org/10.3397/in_2024_3945

43 Saw, L., Ye, Y., Tay, A.: Integration issues of lithium-ion battery into electric vehicles battery pack, J. Clean. Prod., 113, 1032 – 1045, (2015). doi: https://doi.org/10.1016/j.jclepro.2015.11.011

44 Maiorino, A., Cilenti, C., Petruzziello, F., Aprea, C.: A review on thermal management of battery packs for electric vehicles, Appl. Therm. Eng., 238, 122035, (2023). doi: https://doi.org/10.1016/j.applthermaleng.2023.122035

45 Nykvist, B., Nilsson, M.: Rapidly falling costs of battery packs for electric vehicles, Nat. Clim. Change, 5, 329 – 332, (2015). doi: https://doi.org/10.1038/nclimate2564

46 Arjun, P., Perumal, D.: Computational modelling of heat transfer through aluminium metal foams for LiFePO4 battery cooling, Recent Pat. Mech. Eng., 17, 196 – 207, (2024). doi: https://doi.org/10.2174/0122127976289702240212040839

47 Jin, Y., Sun, G., Zhou, G., Chen, R., Wang, J., Yang, Z., et al.: Fabrication of hydroxyl modified hollow glass microsphere composite isocyanate-based polyimide foam and optimization strategy based on different bonding mechanisms, J. Polym. Sci., 63, 443 – 454, (2025). doi: https://doi.org/10.1002/pol.20240796

48 Wachtman, J.: Ceramic innovations in the 20th century, Choice Rev. Online, 37, 37 – 1586, (1999). doi: https://doi.org/10.5860/choice.37-1586

49 Krebs, F., Tromholt, T., Jørgensen, M.: Upscaling of polymer solar cell fabrication using full roll-to-roll processing, Nanoscale, 2, 873 – 886, (2010). doi: https://doi.org/10.1039/b9nr00430k

50 Khouri, N., Bahú, J., Blanco-Llamero, C., Severino, P., Concha, V., Souto, E.: Polylactic acid (PLA): properties, synthesis, and biomedical applications – A review of the literature, J. Mol. Struct., 1309, 138243, (2024). doi: https://doi.org/10.1016/j.molstruc.2024.138243

51 Kechagias, J., Zaoutsos, S.: Effects of 3D-printing processing parameters on FFF parts' porosity: outlook and trends, Mater. Manuf. Process., 39, 804 – 814, (2024). doi: https://doi.org/10.1080/10426914.2024.2304843

52 Bian, X., Tang, J., Li, Z.: Flame retardancy of hollow glass microsphere/rigid polyurethane foams in the presence of expandable graphite, J. Appl. Polym. Sci., 109, 1935 – 1943, (2008). doi: https://doi.org/10.1002/app.27786

53 Andre, T., Couvreur, R., Tamrakar, S., Mielewski, D., Kiziltas, A.: Closed-loop recycling of additive manufacturing waste for value-added automotive foam applications, Polym. Compos., 45, 16383 – 16392, (2024). doi: https://doi.org/10.1002/pc.27340

54 Fu, Y., Wang, X.: Advancements and trends in vehicle sound package for noise control: A comprehensive review, Adv. Mech. Eng., 17, 27, (2025). doi: https://doi.org/10.1177/16878132251345867

55 Kim, G.-S., Feng, T., Hinz, M., Scott, T.: Expanding road noise cancellation to higher frequencies, INTER-NOISE & NOISE-CON Congr. Conf. Proc., 270, 1345 – 1351, (2024). https://doi.org/10.3397/IN_2024_2893

Copyright

Göller Verlag GmbH

Special and Topcial Issues

Special Issue, 3/2025
Guest Editors:
Olaf Krause and Christian Dannert
Advances in Refractories

Topical Issue, 3/2017
Guest Editors:
Waltraud M. Kriven and Gregor J. G. Gluth
Geopolymers

Special Issue, 1/2017
Guest Editor:
Alexander Michaelis
6th International Congress on Ceramics (ICC6)

Topical Issue, 2/2016
Guest Editor:
Christos Aneziris
Low carbon and carbon-free refractory approaches for advan-ced steel technologies; A challenge for refractory materials and systems.

Topcial Issue, 4/2015
Low Temperature Co-fired Ceramics - LTCC

Topcial Issue, 2/2015
Status of Additive Manufacturing with Ceramics

Topical Focus, 4/2014
Materials Processing Science with Lasers as Energy Sources

Topical Issue, 2/2014
Guest Editor:
Christos Aneziris
Low carbon and carbon-free refractory approaches for advanced steel technologies; A challenge for refractory materials and systems.

Special Issue, 2/2013
Guest Editor:
Alexander Michaelis
Ceramic Materials and Components for Energy and Environmental Applications

Topical Issue, 1/2013
Ceramic Processing Science with Lasers as Energy Sources

Printed version

jcst 2015 02 cover

Order journal subscription
 

© 2009-2025 Göller Verlag GmbH