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Journal of Ceramic Science and Technology

The Journal of Ceramic Science and Technology publishes original scientific articles on all topics of ceramic science and technology from all ceramic branches. The focus is on the scientific exploration of  the relationships between processing, microstructure and properties of sintered ceramic materials as well as on new processing routes for innovative ceramic materials. The papers may have either theoretical or experimental background. A high quality of publications will be guaranteed by a thorough double blind peer review process.

The Journal is published by Göller Verlag GmbH on behalf of the Deutsche Keramische Gesellschaft (DKG). Edited by Yu-Ping Zeng, Shanghai Institute of Ceramics, Chinese Academy of Sciences, China.

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Electric-Field-Induced Phase Transition in Mn-Doped (K0.48Na0.48Li0.04)NbO3 Lead-Free Ceramics

H.E. Mgbemere1, G.A. Schneider2, L. Schmitt3, M. Hinterstein4

1 Department of Metallurgical and Materials Engineering, University of Lagos, Lagos Nigeria
2 Institute of Advanced Ceramics, Hamburg University of Technology, Denickestrasse 15, D-21073 Hamburg, Germany
3 Material- und Geowissenschaften,Technische Universität Darmstadt, Darmstadt, Germany
4 Institute for Applied Materials, Karlsruhe Institute for Technology, Karlsruhe, D-76131, Germany

received September 20, 2016, received in revised form November 7, 2016, accepted December 16, 2016

Vol. 8, No. 1, Pages 45-52   DOI: 10.4416/JCST2016-00074

Abstract

In situ applied-electric-field high-resolution X-ray diffraction has been used to study the field-induced response of Mn-doped (K0.48Na0.48Li0.04)NbO3 (KNN-L) ceramics produced using the conventional mixed-oxide processing route. Ferroelectric domains are observed with transmission electron microscopy with indications of nano-segregation of Mn. Rietveld refinement (FULLPROF Suite) is used to refine the diffraction patterns, and a phase change from orthorhombic symmetry with space group Amm2 to tetragonal symmetry with space group P4mm is observed when the applied field exceeds 1.4 kV/mm. Phase coexistence between the two phases is also observed at applied fields between 1.2 kV/mm and 1.3 kV/mm with possible implications of being the coercive field EC value of the sample. A better understanding of the structural behaviour of this type of lead-free ceramics will lead to improvements in their piezoelectric and electromechanical properties.

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Keywords

Keywords: (KxNa1-x)NbO3, high resolution, X-ray diffraction, electric field, lead-free ceramics

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