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Annealing Temperature Effects on Structural and Hydrophilic Properties of Magnesium-Doped TiO2 Thin Films
M. Kumar1, A. K. Gupta1, D. Kumar2
1 Department of Electronics and Communication, National Institute of Technology (NIT), Kurukshetra, India
2 Department of Electronic Science, Kurukshetra University, Kurukshetra, India.
received May 23, 2016, received in revised form July 4, 2016, accepted July 18, 2016
Vol. 7, No. 4, Pages 463-468 DOI: 10.4416/JCST2016-00041
Abstract
Magnesium-doped TiO2 thin films were deposited with the sol-gel spin coating technique. The effects of annealing on the structural and hydrophilic properties were studied. The films deposited on a Corning glass substrate were characterized by means of X-ray diffraction (XRD), UV-visible spectroscopy and Fourier transform infrared spectroscopy. The water contact angle was measured in order to investigate the hydrophilic property of the doped TiO2 films. It was observed that the crystallite structure of the doped TiO2 films improved significantly with increasing temperature. The formation of anatase and rutile phase was observed at 400 °C. The photo-induced hydrophilicity was found to improve for Mg-doped TiO2 film annealed at 500 °C.
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Keywords
TiO2 thin films, Mg-doping, annealing, surface modification, hydrophilicity.
References
1. Mechiakh, R., Sedrine, N. Ben., Karyaoui, M., Chtourou, R.: Annealing temperature effect on the properties of mercury-doped TiO2 films prepared by sol-gel dip-coating technique, Appl. Surf. Sci., 257, 5529 – 5534, (2011).
2. Banerjee, S., Dionysios, D., Pillai, S.C.: Self-cleaning applications of TiO2 by photo-induced hydrophilicity and photocatalysis, Appl. Catal. B- Environ. 176, 396 – 428, (2015).
3. Yaghoubi, H., Taghavinia, N., Alamdari, E.K.: Self cleaning TiO2 coating on polycarbonate: surface treatment, photocatalytic and nano mechanical properties, Surf. Coat. Tech., 204, 1562 – 1568, (2010).
4. Kelvin, Y.S.C., Gregory, K.L.G.: Hydrothermal growth of ferromagnetic Fe-doped TiO2films, Thin Solid Films, 516, 5582 – 5585, (2008).
5. Kumar, M., Kumar, D., Gupta, A.K.: Fe-doped TiO2 thin films for CO gas sensing, J. Electron. Mater. 44, 152 – 157, (2015).
6. Lyson-Sypien, B., Radecka, M., Rekas, M., Swierczek, K., Michalow-Mauke, K., Graule, T., Zakrzewska, K.: Grain-size-dependent gas-sensing properties of TiO2 nanomaterials, Sens. Act. B- Chem. 211, 67 – 76, (2015).
7. Akpan, U.G., Hameed, B.H.: The advancements in sol-gel method of doped-TiO2 photocatalysts, Appl. Catal. A- Gen. 375, 1 – 11, (2010).
8. Korotcenkov, G.: Metal oxides for solid-state gas sensors: what determines our choice?, Mater. Sci. Eng. B.- Solid, 139, 1 – 23, (2007).
9. Siwinska-Stefanska, K., Paukszta, D., Piasecki, A., Jesionowski, T.: Synthesis and physicochemical characteristics of titanium dioxide doped with selected metals, Physicochem. Probl. Mi., 50, 265 – 276, (2014).
10. Li, D., Wang, S., Wang, J., Zhang, X., Liu, S.: Synthesis of CdTe/TiO2 nanoparticles and their photocatalytic activity, Mater. Res. Bull., 48, 4283 – 4286, (2013).
11. Kumar, M., Gupta, A.K., Kumar, D.: Mg-doped TiO2 thin films deposited by low cost technique for CO gas monitoring, Ceram. Int., 42, 405 – 410, (2016).
12. Venkatachalam, N., Palanichamy, M., Murugesan, V.: Sol-gel preparation and characterization of alkaline earth metal doped nanoTiO2: efficient photocatalytic degradation of 4-chlorophenol, J. Mol. Catal. A.-Chem., 273, 177 – 185, (2007).
13. Cheong, Y.L., Yam, F.K., Ng, S.W., Hassan. Z., Ng, S.S., Low, I.M.: Fabrication of titanium dioxide nanotubes in fluoride-free electrolyte via rapid breakdown anodization, J. Porous Mat., 22:1437 – 1444, (2015).
14. Carneiro, J.O., Teixeira., V, Portinha, A., Dupák. L, Magalhães, A, Coutinho, P.: Study of the deposition parameters and Fe-dopant effect in the photocatalytic activity of TiO2 films prepared by dc reactive magnetron sputtering, Vacuum, 78, 37 – 46, (2005).
15. Alexandrescu, R., Morjan, I., Scarisoreanu. M., Birjega, R., Popovici, E., Soare, I., Gavrila-Florescu, L., Voicu, I., Sandu. I., Dumitrache, F., Prodan, G., Vasile, E., Figgemeier, E.: Structural investigations on TiO2 and Fe-doped TiO2 nanoparticles synthesized by laser pyrolysis, Thin Solid Films, 515, 8438 – 8445, (2007).
16. Kumar, M., Kumar, D.: The deposition of nanocrystallineTiO2 thin film on silicon using sol-gel technique and its characterization, Microelectron. Eng., 87, 447 – 450, (2010).
17. Yang, L., Zhang, M., Shi, S., Lv, J., Song, X., He, G., Sun, Z.: Effect of annealing temperature on wettability of TiO2 nanotube array films, Nano. Res. Lett., 9, 1 – 7, (2014).
18. Hashimoto, K., Irie, H., Fujishima, A.: TiO2 photocatalysis: A historical overview and future prospects. Jpn. J. Appl. Phys., 44, 8269, (2005).
19. Ahmad, M.K., Halid, M.L.M., Rasheid, N.A., Ahmed, A.Z., Abdullah, S., Rusop, M.: Effect of annealing temperatures on surface morphology and electrical properties of titanium dioxide thin films prepared by sol gel method, J. Susta. Energy Envi., 1, 17 – 20, (2010).
20. Wang, J.J., Wang, D.S., Wang, J., Zhao, W.L., Wang, C.W.: High transmittance and superhydrophilicity of porous TiO2/SiO2 bi-layer films without UV irradiation, Surf. Coat. Tech., 205, 3596 – 3599, (2011).
21. Varghese, O.K., Gong, D., Paulose, M., Grimes, C.A., Dickey, E.C.: Crystallization and High-Temperature Structural Stability of Titanium Oxide Nanotube Arrays, J. Mat. Res., 18, 156 – 165, (2011).
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