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Journal of Ceramic Science and Technology

The Journal of Ceramic Science and Technology publishes original scientific articles on all topics of ceramic science and technology from all ceramic branches. The focus is on the scientific exploration of  the relationships between processing, microstructure and properties of sintered ceramic materials as well as on new processing routes for innovative ceramic materials. The papers may have either theoretical or experimental background. A high quality of publications will be guaranteed by a thorough double blind peer review process.

The Journal is published by Göller Verlag GmbH on behalf of the Deutsche Keramische Gesellschaft (DKG). Edited by Yu-Ping Zeng, Shanghai Institute of Ceramics, Chinese Academy of Sciences, China.

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On the Synthesis of Low-Cost, Titanium-Based MXenes

C. Li1, S. Kota2, C. Hu2, M.W. Barsoum2

1 Light Industry College of Liaoning University, Shenyang 110036, China
2 Department of Materials Science and Engineering, Drexel University, Philadelphia, Pennsylvania, USA 19104

received May 31, 2016, received in revised form July 17, 2016, accepted July 19, 2016

Vol. 7, No. 3, Pages 301-306   DOI: 10.4416/JCST2016-00042

Abstract

Herein we report methods to synthesize two MAX phases, Ti2AlC and Ti3AlC2, starting with rutile (TiO2), graphite and aluminum powders as raw materials. Adjusting the initial ratios of the raw materials led to the synthesis of multi-phase mixtures containing predominantly Ti2AlC-Al2O3 or Ti3AlC2-Al2O3. Free-standing Ti2CTx and Ti3C2Tx MXene films were successfully produced by etching the powders in a solution of hydrochloric acid with pre-dissolved lithium fluoride followed by sonication in water to produce colloidal suspensions of atomically thin MXene flakes. The Ti3C2Tx films produced from the lower-cost precursors retained the high electrical conductivity previously reported for this material. Since starting with rutile instead of Ti metal powders reduces the cost of the raw materials by a factor of about 2.6, this new, scalable approach to MXene synthesis is more economical.

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Keywords

MAX phase, MXene, ceramics, 2D materials, nanomaterials

References

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