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Journal of Ceramic Science and Technology

The Journal of Ceramic Science and Technology publishes original scientific articles on all topics of ceramic science and technology from all ceramic branches. The focus is on the scientific exploration of  the relationships between processing, microstructure and properties of sintered ceramic materials as well as on new processing routes for innovative ceramic materials. The papers may have either theoretical or experimental background. A high quality of publications will be guaranteed by a thorough double blind peer review process.

The Journal is published by Göller Verlag GmbH on behalf of the Deutsche Keramische Gesellschaft (DKG). Edited by Yu-Ping Zeng, Shanghai Institute of Ceramics, Chinese Academy of Sciences, China.

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Effect of Repeated Firing on the Resistance of Screen-Printed Thick-Film Conductors

D. Ortolino, A. Engelbrecht, H. Lauterbach, M. Bräu, J. Kita, R. Moos

Department of Functional Materials, University of Bayreuth, Germany

received July 24, 2014, received in revised form October 1, 2014, accepted October 6, 2014

Vol. 5, No. 4, Pages 317-326   DOI: 10.4416/JCST2014-00029

Abstract

In this paper, the effect of repeated sintering cycles on the resistance of four different thick-film conductor pastes was investigated. Silver, gold, silver-platinum and silver-palladium pastes are widely used in thick-film technology. Their electrical resistance (R) and their temperature coefficient of resistance (TCR) are important material properties. Screen-printed metallization layers were fired repeatedly and their electrical resistance was measured simultaneously during heating and cooling. It was found that the resistances change with increasing number of firing steps and that they run asymptotically to a final value. Light-optical and SEM-EDX analyses explained this behavior. Inorganic compounds of the paste diffuse into the ceramic substrate. The diffusion follows a parabolic diffusion law. A strong correlation between material diffusion and resistance change is found.

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Keywords

Thick-film, screen-printing, conductor, gold, silver, silver-palladium, silver-platinum, resistance, TCR, temperature cycling, firing, sintering, material diffusion

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